In nature, CO2 is exchanged continually between the atmosphere, plants and animals through photosynthesis, respiration, and decomposition, and between the atmosphere and ocean through gas exchange. A very small amount of CO2 (roughly 1% of the emission rate from fossil fuel combustion) is also emitted in volcanic eruptions. This is balanced by an equivalent amount that is removed by chemical weathering of rocks. The CO2 level in 2012 was about 40% higher than it was in the nineteenth century. Most of this CO2 increase has taken place since 1970, about the time when global energy consumption accelerated. Measured decreases in the fraction of other forms of carbon (the isotopes 14C and 13C) and a small decrease in atmospheric oxygen concentration (observations of which have been available since 1990) show that the rise in CO2 is largely from combustion of fossil fuels (which have low 13C fractions and no 14C). Deforestation and other land use changes have also released carbon from the biosphere (living world) where it normally resides for decades to centuries. The additional CO2 from fossil fuel burning and deforestation has disturbed the balance of the carbon cycle, because the natural processes that could restore the balance are too slow compared to the rates at which human activities are adding CO2 to the atmosphere. As a result, a substantial fraction of the CO2 emitted from human activities accumulates in the atmosphere, where some of it will remain not just for decades or centuries, but for thousands of years. Comparison with the CO2 levels measured in air extracted from ice cores indicates that the current concentrations are higher than they have been in at least 800,000 years (see Question 6).

If emissions of CO2 stopped altogether, it would take many thousands of years for atmospheric CO2 to return to ‘pre-industrial’ levels due to its very slow transfer to the deep ocean and ultimate burial in ocean sediments. Surface temperatures would stay elevated for at least a thousand years, implying extremely long-term commitment to a warmer planet due to past and current emissions, and sea level would likely continue to rise for many centuries even after temperature stopped increasing [Figure 9]. Significant cooling would be required to reverse melting of glaciers and the Greenland ice sheet, which formed during past cold climates. The current CO2-induced warming of Earth is therefore essentially irreversible on human timescales. The amount and rate of further warming will depend almost entirely on how much more CO2 humankind emits.

Measurements of air in ice cores show that for the past 800,000 years up until the 20th century, the atmospheric CO2 concentration stayed within the range 170 to 300 parts per million (ppm), making the recent rapid rise to nearly 400 ppm over 200 years particularly remarkable [figure 3]. During the glacial cycles of the past 800,000 years both CO2 and methane have acted as important amplifiers of the climate changes triggered by variations in Earth’s orbit around the Sun. As Earth warmed from the last ice age, temperature and CO2 started to rise at approximately the same time and continued to rise in tandem from about 18,000 to 11,000 years ago. Changes in ocean temperature, circulation, chemistry and biology caused CO2 to be released to the atmosphere, which combined with other feedbacks to push Earth into an even warmer state. For earlier geological times, CO2 concentrations and temperatures have been inferred from less direct methods. Those suggest that the concentration of CO2 last approached 400 ppm about 3 to 5 million years ago, a period when global average surface temperature is estimated to have been about 2 to 3.5°C higher than in the pre-industrial period. At 50 million years ago, CO2 may have reached 1000 ppm, and global average temperature was probably about 10°C warmer than today. Under those conditions, Earth had little ice, and sea level was at least 60 metres higher than current levels.

Our understanding of the physics by which CO2 affects Earth’s energy balance is confirmed by laboratory measurements, as well as by detailed satellite and surface observations of the emission and absorption of infrared energy by the atmosphere. Greenhouse gases absorb some of the infrared energy that Earth emits in so-called bands of stronger absorption that occur at certain wavelengths. Different gases absorb energy at different wavelengths. CO2 has its strongest heat-trapping band centred at a wavelength of 15 micrometres (millionths of a metre), with wings that spread out a few micrometres on either side. There are also many weaker absorption bands. As CO2 concentrations increase, the absorption at the centre of the strong band is already so intense that it plays little role in causing additional warming. However, more energy is absorbed in the weaker bands and in the wings of the strong band, causing the surface and lower atmosphere to warm further.